Journal
NANO LETTERS
Volume 10, Issue 11, Pages 4762-4766Publisher
AMER CHEMICAL SOC
DOI: 10.1021/nl1034545
Keywords
Catalytic CO oxidation; CuO nanowires; plasma enhancement; Cu oxidation states
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Funding
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001060]
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We report the first experimental study of catalytic CO oxidation over copper oxide (CuO) nanowires (NWs) grown directly on copper meshes. The catalytic activity of CuO NWs is significantly improved by a brief argon or hydrogen radio frequency plasma treatment. The plasma enhancement effect comes from the generation of grain boundaries and the reduction of Cu(II) to the more active oxidation state Cu(I) according to our TEM. XPS, and kinetic study.
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