Journal
NANO LETTERS
Volume 9, Issue 1, Pages 57-61Publisher
AMER CHEMICAL SOC
DOI: 10.1021/nl802310k
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Funding
- Chevron through the Stanford-Chevron Program on Diamondoid Nano-Science
- U.S. Department of Energy
- Office of Basic Energy Science, Division of Material Science and Engineering
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Recent photoemission experiments have discovered a highly monochromatized secondary electron peak emitted from diamondoid self-assembled monolayers on metal substrates. New experimental data and simulation results are presented to show that a combination of negative electron affinity and strong electron-phonon scattering is responsible for this behavior. The simulation results are generated using a simple Monte Carlo transport algorithm. The simulated spectra recreate the main spectral features of the measured ones.
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