4.2 Article

Acetylation of alcohols and phenols by zinc zirconium phosphate as an efficient heterogeneous catalyst under solvent-free conditions

Journal

MONATSHEFTE FUR CHEMIE
Volume 145, Issue 9, Pages 1461-1472

Publisher

SPRINGER WIEN
DOI: 10.1007/s00706-014-1222-9

Keywords

Zinc zirconium phosphate; Heterogeneous catalysis; Solvent-free; Acetylation; Alcohols; Phenols

Funding

  1. Isfahan University of Technology (IUT), Iran
  2. Center of Excellence in Sensor and Green Chemistry Research (IUT)

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An efficient method for the acetylation of a wide range of alcohols as well as phenols with acetic anhydride in good to excellent yields under solvent-free conditions, using zinc zirconium phosphate as the catalyst was investigated. The catalyst was characterized by XRD, inductivity coupled plasma-optical emission spectroscopy, and scanning electron microscope. Products are easily isolated and the protocol is mild and green, compared to the existing methods.

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