Journal
MONATSHEFTE FUR CHEMIE
Volume 144, Issue 3, Pages 313-319Publisher
SPRINGER WIEN
DOI: 10.1007/s00706-012-0812-7
Keywords
Gold-NHC complexes; Medicinal inorganic chemistry; Antimicrobial; Benzimidazol-2-ylidene
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Funding
- Technological and Scientific Research Council of Turkey TUBITAK [TBAG (108T411)]
- Inonu University Research Fund [IUBAP: 2009/13]
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Benzimidazolium salts and six anionic gold-NHC complexes (NHC = N,N'-dialkylbenzimidazol-2-ylidene) were prepared and characterized. Novel [Au(NHC)(2)]AuCl2-type complexes were prepared in good yields from silver-NHC complexes by treatment with [AuCl(PPh3)], following the commonly used silver carbene transfer route. All compounds were characterized using H-1 and C-13 NMR spectroscopy, elemental analysis, and IR. The gold complexes showed antimicrobial activity against Gram-positive/negative and fungal strains.
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