Journal
MONATSHEFTE FUR CHEMIE
Volume 143, Issue 9, Pages 1263-1274Publisher
SPRINGER WIEN
DOI: 10.1007/s00706-012-0772-y
Keywords
Au-Ge-Ni; Thermodynamic; Phase diagram; CALPHAD
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Funding
- Swiss State Secretariat for Education and Research (SBF) [C08.0031]
- Swiss National Science Foundation (SNSF) [200021 134575/1]
- Swiss National Science Foundation (SNF) [200021_134575] Funding Source: Swiss National Science Foundation (SNF)
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Phase equilibria in the Au-Ge-Ni ternary system were studied by means of scanning electron microscopy, electron probe microanalysis, X-ray diffraction, and differential scanning calorimetry. The phase relations in the solid state at 600 A degrees C as well as a vertical section at Au72Ge28-Ni were established. No ternary compound was found at 600 A degrees C. On the basis of the experimental phase equilibria data, a thermodynamic model of the Au-Ge-Ni ternary system was developed using the CALPHAD method. Thermodynamically calculated phase diagrams are shown at 600 A degrees C, in two vertical sections and the liquidus projection. Reasonable agreement between the calculations and the experimental results was achieved.
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