Journal
MONATSHEFTE FUR CHEMIE
Volume 141, Issue 3, Pages 351-356Publisher
SPRINGER WIEN
DOI: 10.1007/s00706-010-0266-8
Keywords
Phosphonato esters; Diastereoselective synthesis; Karplus equation; Biological activity
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Funding
- Research Council of the University of Sistan and Baluchestan
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Synthesis of five phosphonato esters has been accomplished via reaction between dimethyl acetylenedicarboxylate and triphenyl phosphite in the presence of biological compounds such as theophylline, 4-hydroxypyrimidine, 2H-3,1-benzoxazine-2,4(1H)-dione, 2-chloroaniline, or 3-nitroaniline at ambient temperature. The configuration of the compounds was determined on the basis of coupling constants emerging from the Karplus equation.
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