Journal
MONATSHEFTE FUR CHEMIE
Volume 140, Issue 12, Pages 1437-1445Publisher
SPRINGER WIEN
DOI: 10.1007/s00706-009-0215-6
Keywords
Olefin oxidation; Hydrogen peroxide; Coordination polymer; Manganese
Categories
Funding
- Zanjan and Tarbiat Modares Universities
- DFG [Ja466/14-1/2]
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The Mn(II) dicarboxylate coordination polymers [Mn(mu-terephthalate)(H2O)(2)](n), [Mn(mu-oxalate)(H2O)(2)](n), and [Mn(mu-D-(-)-tartrate)](n) were prepared in water and characterized by FT-IR spectroscopy and CHN analysis. Particles of the terephthalate catalyst were also synthesized, by reaction of terephthalic acid and MnCl2 center dot 4H(2)O by a sonochemical method. The catalytic potential of these coordination polymers as slow-release sources of catalytically active Mn species was tested in the oxidation of cyclooctene to its epoxide in acetonitrile, using hydrogen peroxide as oxygen source. For the terephthalate species the catalytic activity was found to increase with increasing dielectric constant and dipole moment of the solvent (being highest in acetonitrile), with reaction temperature to a maximumat 60 degrees C, and with an imidazole co-catalyst (highest activity found for a imidazole-to-catalyst molar ratio of 20:1). Good activity with more than 64% conversion in 24 h was obtained for epoxidation of cyclooctene and cyclohexene, whereas low yields only were obtained from aryl-substituted olefins. Some exo versus endo regioselectivity was found for norbornene.
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