Journal
MOLECULES
Volume 19, Issue 3, Pages 3804-3812Publisher
MDPI AG
DOI: 10.3390/molecules19033804
Keywords
Callyspongia sp; polyunsaturated fatty acid; EPA; DHA; iodolactonization; synthesis; marine sponge metabolite
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The synthesis of the marine natural product 1,6Z,9Z,12Z,15Z-octadecapentaen-3-one (1) has been achieved by two different routes starting from the ethyl esters of eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA), respectively. Using EPA ethyl ester as starting material the polyunsaturated vinyl ketone lipid 1 was obtained in 17% overall yield.
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