Journal
MOLECULES
Volume 18, Issue 1, Pages 14-26Publisher
MDPI
DOI: 10.3390/molecules18010014
Keywords
asymmetric conjugate addition; rhodium catalyst; bidentate phosphoramidite ligand
Funding
- Grants-in-Aid for Scientific Research [22550092] Funding Source: KAKEN
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A new bidentate phosphoramidite (N-Me-BIPAM) based on Shibasaki's N-linked BINOL was synthesized. This ligand appears to be highly effective for rhodium-catalyzed asymmetric conjugated addition of arylboronic acids to alpha,beta-unsaturated enones. The reaction of ortho-substituted arylboronic acid with acyclic and cyclic enones provides the corresponding products in good yields and enantioselectivities.
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