Journal
MOLECULES
Volume 16, Issue 5, Pages 4191-4230Publisher
MDPI
DOI: 10.3390/molecules16054191
Keywords
organobismuth compounds; synthesis; properties; reagent; catalyst
Funding
- National Natural Science Foundation of China [20877040]
- Technological Supporting Foundation of Jiangsu Province [BE2009144]
- China-Israel Joint Research Program [5]
- Enviromental Protection Department of Jiangsu Province of China [201001]
- Fourth Technological Development Scheming (Industry) Program of Suzhou City of China [SYG201006]
- Fundamental Research Funds for the Central Universities
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Organobismuth chemistry was emphasized in this review article due to the low price, low toxicity and low radioactivity characteristics of bismuth. As an environmentally-friendly class of organometallic compounds, different types of organobismuth compounds have been used in organic synthesis, catalysis, materials, etc. The synthesis and property characterization of many organobismuth compounds had been summarized. This review article also presented a survey of various applications of organobismuth compounds in organic transformations, as reagents or catalysts. The reactivity, reaction pathways and mechanisms of reactions with organobismuths were discussed. Less common and limiting aspects of organobismuth compounds were also briefly mentioned.
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