Journal
MOLECULES
Volume 16, Issue 11, Pages 9495-9504Publisher
MDPI AG
DOI: 10.3390/molecules16119495
Keywords
chemical functionalization; La(2)@I(h)-C(80); carbohydrate; diazirine; glycoconjugate
Funding
- The Next Generation Super Computing Project (Nanoscience Project), Nanotechnology Support Project
- Ministry of Education, Culture, Sports, Science, and Technology of Japan [22000009]
- JST
- MICINN
- [20108001]
- [20245006]
- [22750030]
- [20036008]
- [20038007]
- Grants-in-Aid for Scientific Research [20108002, 22750030, 20108001, 20245006, 23750035] Funding Source: KAKEN
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Endohedral metallofullerene glycoconjugates were synthesized under mild conditions by carbene addition using appropriate glycosylidene-derived diazirine with La(2)@I(h)-C(80). NMR spectroscopic studies revealed that the glycoconjugate consists of two diastereomers of [6,6]-open mono-adducts. The electronic properties were characterized using Vis/NIR absorption spectroscopy and electrochemical measurements. This study demonstrates that glycosylidene carbene is useful to incorporate carbohydrate moieties onto endohedral metallofullerene surfaces.
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