Journal
MOLECULES
Volume 15, Issue 5, Pages 3441-3461Publisher
MOLECULAR DIVERSITY PRESERVATION INTERNATIONAL-MDPI
DOI: 10.3390/molecules15053441
Keywords
palladium; nanoparticles; ionic liquids; cross-coupling; Heck; Suzuki; Stille; Sonogashira; Ullmann
Funding
- Alexander-von-Humboldt Foundation
- CNPq
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A brief summary of selected pioneering and mechanistic contributions in the field of carbon-carbon cross-coupling reactions with palladium nanoparticles (Pd-NPs) in ionic liquids (ILs) is presented. Five exemplary model systems using the Pd-NPs/ILs approach are presented: Heck, Suzuki, Stille, Sonogashira and Ullmann reactions which all have in common the use of ionic liquids as reaction media and the use of palladium nanoparticles as reservoir for the catalytically active palladium species.
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