Journal
MOLECULES
Volume 15, Issue 4, Pages 2667-2685Publisher
MDPI
DOI: 10.3390/molecules15042667
Keywords
Mizoroki-Heck reaction; palladium; 1,2-dienes; 1,3-dienes
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This review is an overview of the last ten years' use of the Mizoroki-Heck coupling applied to 1,2- and 1,3-dienes. Since both these systems form pi-allyl palladium intermediates in Pd(0) coupling, they show particular chemical behavior. Many examples of 1,2-dienes Heck reactions are presented. 1,2-Dienes are important substrates because of their high reactivity that makes them useful building blocks for the synthesis of biologically relevant structures.
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