Journal
MOLECULES
Volume 15, Issue 8, Pages 5782-5796Publisher
MDPI
DOI: 10.3390/molecules15085782
Keywords
alpha-aminophosphonate derivatives; aldimines; cinnamaldehyde; chiral organocatalyst; asymmetric addition
Funding
- National Key Project for Basic Research [2010CB126105]
- National Natural Science Foundation of China [20872002]
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Asymmetric addition under mild conditions of dialkyl phosphites on aldimines derived from cinnamaldehyde catalyzed by the inexpensive chiral organocatalyst (R)-3,3'-[4-fluorophenyl](2)-1,1'-binaphthol phosphate has been found effective to give new alpha-amino-phosphonates 9 in moderate yields (30-65%) and enantiomeric excess (8.4%-61.9%).
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