Journal
MOLECULAR DIVERSITY
Volume 13, Issue 2, Pages 209-239Publisher
SPRINGER
DOI: 10.1007/s11030-008-9103-y
Keywords
Fluorous biphasic catalysis; Fluorous Lewis acids; Metal perfluorooctanesulfonates; Metal bis(perfluorooctanesulfonyl)amides; Fluorous phase transfer catalysis; Fluorous onium salts; Fluorous crown ethers
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The new phase-separation and immobilization technique known as fluorous biphase system (FBS) has become an active topic among researchers in both industry and academia. A series of fluorous biphasic reactions catalyzed by Lewis acid-type metal perfluorooctanesulfonates and metal bis(perfluorooctanesulfonyl) amides are reviewed in this paper. The recent development of fluorous phase transfer catalyst (PTC) is also discussed.
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