Journal
MOLECULAR CRYSTALS AND LIQUID CRYSTALS
Volume 552, Issue -, Pages 217-227Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/15421406.2011.619097
Keywords
Cu(II) complexes; enantiotropic; nematic; orthogonal smectic A; Schiff bases
Funding
- Universiti Sains Malaysia [203/PKIMIA/6711192, 1001/PKIMIA/822208]
Ask authors/readers for more resources
A new homologous series of bidentate Schiff bases 5-alkoxy-2-((4-(phenyldiazenyl) phenylimino)methyl) phenol and their Cu(II) complexes have been synthesized and characterized by spectroscopic techniques along with studies on the mesomorphic properties. Phase transitions of all the Schiff bases and Cu(II) complexes in this series are enantiotropic. The ligands with n-octyloxy and n-decyloxy flexible chains exhibit the nematic (N) and smectic A (SmA) phases, the latter of which is characterized by focal conic fan-shaped texture. In contrast, the Cu(II) complexes show exclusively the SmA phase, which is ascribed to the presence of Cu-O and Cu-N coordination modes. For the same reason, the thermal stabilities of the complexes have also been improved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available