Journal
SCIENCE CHINA-CHEMISTRY
Volume 58, Issue 8, Pages 1329-1333Publisher
SCIENCE PRESS
DOI: 10.1007/s11426-015-5377-y
Keywords
C-H bond activation; photoinduced; free radical; aryl iodide
Categories
Funding
- National Basic Research Program of China [2011CB932404, 2011CBA00501]
- National Natural Science Foundation of China [21332001, 21431008, 21301173]
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Two general protocols have been developed for the photoinduced, metal-free direct arylation of unactivated arenes with aryl iodide. Both methods gave good to excellent yields for most substrates. Notably, the C-F bond in method A and the C-F, C-Cl, and C-Br bonds in method B could survive the arylation reaction. These methods offered excellent options for syntheses of biaryls.
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