Journal
SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS
Volume 16, Issue 5, Pages -Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1088/1468-6996/16/5/054202
Keywords
metal-organic frameworks; solvothermal synthesis; microwave-assisted synthesis; electrochemical synthesis; post-synthetic modification; post-synthetic exchange
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Funding
- Center for Gas Separations Relevant to Clean Energy Technologies, an Energy Frontier Research Center - US Department of Energy, Office of Science, and Office of Basic Energy Sciences [DE-SC0001015]
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d Metal-organic frameworks (MOFs) have attracted considerable attention for various applications due to their tunable structure, porosity and functionality. In general, MOFs have been synthesized from isolated metal ions and organic linkers under hydrothermal or solvothermal conditions via one-spot reactions. The emerging precursor approach and kinetically tuned dimensional augmentation strategy add more diversity to this field. In addition, to speed up the crystallization process and create uniform crystals with reduced size, many alternative synthesis routes have been explored. Recent advances in microwave-assisted synthesis and electrochemical synthesis are presented in this review. In recent years, post-synthetic approaches have been shown to be powerful tools to synthesize MOFs with modified functionality, which cannot be attained via de novo synthesis. In this review, some current accomplishments of post-synthetic modification (PSM) based on covalent transformations and coordinative interactions as well as post-synthetic exchange (PSE) in robust MOFs are provided.
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