Journal
MINI-REVIEWS IN ORGANIC CHEMISTRY
Volume 6, Issue 2, Pages 95-104Publisher
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/157019309788167738
Keywords
Alkanes; olefins; aromatics; epoxidation; metal-complex catalysis; alkyl hydroperoxides
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Funding
- Russian Foundation for Basic Research [06-03-32344-a]
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Recent works devoted to the oxygenations of saturated, aromatic as well as olefinic hydrocarbons are surveyed, and the emphasis is made on the author's own publications. Both soluble metal complexes and solid metal compounds catalyze oxidative transformations of hydrocarbons. Hydrogen peroxide, alkyl peroxides, and peroxy acids were used in these reactions as oxidants. The catalytic systems often include obligatory co-catalysts, for example, nitrogen-containing bases or acids (inorganic, carboxylic or amino acids).
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