Journal
MINI-REVIEWS IN ORGANIC CHEMISTRY
Volume 6, Issue 3, Pages 168-183Publisher
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/157019309788922720
Keywords
Carbamates; organic carbonates; phosgene substitution; carbonylation; catalysis
Categories
Funding
- Universita di Bari (Fondi di Ateneo)
- MiUR [PRIN 2006031888 001]
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Aminolysis of organic carbonates is a suitable phosgene-free synthetic route to carbamate esters. The paper reviews recent advances in this field. Emphasis is laid on the reaction of amines with industrially relevant carbonic acid diesters, (MeO)(2)CO, (PhO)(2)CO, MeOC(O)OPh, currently obtainable without using phosgene. The carbonylation process may require a catalyst. The use of effective catalytic systems is highlighted and their mode of action is discussed.
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