Journal
MINI-REVIEWS IN MEDICINAL CHEMISTRY
Volume 13, Issue 6, Pages 824-835Publisher
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/1389557511313060005
Keywords
Transition metal catalyst; P(O)-H compound; carbon-carbon unsaturated compound; regio- and stereoselective addition; carbon-H and heteroatom-H compounds; dehydrogenative coupling reactions; well-defined functional organophosphorus compound
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Organophosphorus compounds are of high importance in organic synthesis, catalysis, biochemistry, pharmaceuticals, and material science. In this mini review, we summarize our recent studies on transition metal-catalyzed green and atom efficient transformations of P(O)-H bonds to various versatile organophosphorus compounds, including the highly regio- and stereoselective P(O)-H additions to carbon-carbon unsaturated compounds, asymmetric hydrophosphorylation reactions, and dehydrogenative coupling reactions of P(O) H compounds with carbon-H and heteroatom-H compounds. These new reactions provide efficient, general and practical ways for the preparation of a variety of well-defined functional organophosphorus compounds. Mechanistic aspects related to the catalytic processes are also discussed.
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