Journal
MICROPOROUS AND MESOPOROUS MATERIALS
Volume 193, Issue -, Pages 160-165Publisher
ELSEVIER
DOI: 10.1016/j.micromeso.2014.03.003
Keywords
MIL-101; Metal-organic framework (MOE); Hydrogen storage; Acetylene storage; C2 hydrocarbon separation
Categories
Funding
- Synthesis of Porous Hybrids and their Applications [KK-1301-F0]
- Korea Research Institute of Chemical Technology (KRICT)
- KCRC [Korea CCS 2020]
- NRF
- Center for Hybrid Interface Materials (HIM) for the Global Frontier RD Program [2013-073298]
- Ministry of Science, ICT & Future Planning
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education [2012R1A6A3A03040053]
- National Research Foundation of Korea [2012R1A6A3A03040053] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Ask authors/readers for more resources
The effect of purification condition of a chromium terephthalate MIL-101 on gas storage (H-2, CO2, and C2H2) and C2 hydrocarbon separations was investigated for MIL-101a, MIL-101b, and MIL-101c, which were obtained by three-step sequential purification using hot water/ethanol and aqueous NH4F solution treatments. MIL-101c was the best in terms of gas storage capacities among the three samples possibly due to the removal of free and coordinated terephthalic acids. Remarkably, MIL-101c exhibits among the highest total hydrogen uptake at 50 bar and 77 K (9.9 wt%) and shows considerably large deliverable capacity between 1.5 and 50 bar (7.6 wt%). Moreover, MIL-101c shows among the highest C2H2 storage capacity (6.4 mmol g(-1)) and deliverable capacity (4.3 mmol g(-1)) at 1 bar and 313 K. For C2H2/C2H6, C2H2/C2H4, and C2H4/C2H6 separations, MIL-101c exhibits higher adsorption capacities, working capacities and adsorption figure of merit (AFM) values while MIL-101b shows higher selectivities and sorbent selection parameters. These results clearly show that a proper purification of MIL-101 is important for gas storage and gas separations. (C) 2014 Elsevier Inc. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available