Journal
MICROPOROUS AND MESOPOROUS MATERIALS
Volume 157, Issue -, Pages 89-93Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.micromeso.2012.01.015
Keywords
Porous coordination polymer; Metal-organic framework; Water adsorption; Heat transformation
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Funding
- Grants-in-Aid for Scientific Research [23750157] Funding Source: KAKEN
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Four MIL-101-type porous coordination polymers were synthesized containing different substituents (-H, -NO2, -NH2, -SO3H) in the ligand and their water sorption properties were investigated. All of the compounds adsorbed huge amounts of water (ca. 0.8-1.2 g g(-1)) and the adsorbed water can be released at relatively low temperatures (ca. 353 K). In addition, the trapping pressure of water adsorption was found to be controlled by changing the substituents, varying the hydrophobicity of the functional groups. (C) 2012 Elsevier Inc. All rights reserved.
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