Journal
MICROPOROUS AND MESOPOROUS MATERIALS
Volume 149, Issue 1, Pages 166-171Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.micromeso.2011.06.037
Keywords
SnO2; SBA-15; Accessibility; Rhodamine B; Photodegradation
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We address the accessibility of tin oxide (SnO2) nanoparticles synthesized inside the pores of mesoporous silica (SBA-15) host. On using a low-temperature route for in situ synthesis of SnO2 and hence eliminating interparticle aggregation, SnO2 nanoparticles of diameter much smaller (3.5 nm) than the cylindrical pore diameter (6.3 nm) of the SBA-15 could be synthesized. This enables molecules diffusing into the SBA-15 pores to access the very high specific surface area of SnO2: enabling the diffusing species to react easily with the latter. This is demonstrated by an enhanced photocatalytic degradation rate constant of an aqueous solution of rhodamine B dye, on contacting the latter with the SnO2-SBA-15 composite. (C) 2011 Elsevier Inc. All rights reserved.
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