Journal
MICROPOROUS AND MESOPOROUS MATERIALS
Volume 132, Issue 1-2, Pages 300-303Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.micromeso.2010.02.023
Keywords
Hydrogen storage; Metal-organic framework (MOF); Isosteric heat of adsorption; Grand canonical Monte Carlo (GCMC) simulation
Categories
Funding
- Department of Energy [DE-FG36-08GO18137]
Ask authors/readers for more resources
Hydrogen storage and delivery in eight representative metal organic frameworks (MOFs) was investigated using grand canonical Monte Carlo (GCMC) simulations. The simulations demonstrate that the optimal isosteric heat of adsorption (Q(st)) for maximum hydrogen delivery using MOFs is approximately 20 kJ/mol. The results also suggest that increasing the Q(st) for MOFs with large surface areas (>4800 m(2)/g) is required to attain current hydrogen storage targets in terms of deliverable capacity. (C) 2010 Elsevier Inc. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available