Journal
MICRON
Volume 41, Issue 7, Pages 687-694Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.micron.2010.06.005
Keywords
X-ray Absorption Spectroscopy; EELS; ELNES; XANES; Ledges; Transition metal compounds
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Funding
- Netherlands National Science Foundation
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The CTM4XAS program for the analysis of transition metal L edge Electron Energy Loss Spectroscopy (EELS) or X-ray Absorption Spectra (XAS) is explained. The physical background of the calculations is briefly discussed. The program consists of three theoretical components, based on, respectively, atomic multiplet theory, crystal field theory and charge transfer theory. The theoretical concepts are explained and a number of examples are presented. The calculation of the 2p EELS and XAS spectra of transition metal ions, is given in detail, including their Magnetic Circular Dichroism (MCD). In addition, examples of is, 2s, 3s, 2p and 3p X-ray Photoemission Spectroscopy (XPS) are given. (c) 2010 Elsevier Ltd. All rights reserved.
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