Journal
MICROCHIMICA ACTA
Volume 175, Issue 3-4, Pages 291-299Publisher
SPRINGER WIEN
DOI: 10.1007/s00604-011-0674-4
Keywords
Palladium; Solid phase extraction; 1-(2-Pyridylazo)-2-naphthol; Modified magnetite nanoparticles
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Funding
- Research Council of the University of Mohaghegh Ardabili
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We report on a method for selective extraction and backextraction for the ultra-sensitive determination of Pd(II). Magnetite nanoparticles modified with sodium dodecyl sulfate were used to extract Pd(II) as its green 1-(2-pyridylazo)-2-naphtholate complex prior to zero- and first-derivative spectrophotometric determination at 659 and 681 nm, respectively. A sample volume of 70 mL was backextracted with 0.50 mL of n-butanol in a 3-phasic system. The effects of reaction time and the other variables were optimized. The enrichment factor is 134 and the calibration plots are linear in the range from 2 to 90 ng mL(-1) of Pd(II). The detection limit is 0.3 ng mL(-1) and the relative standard deviations and recoveries at levels of 10 and 72 ng mL(-1) of Pd(II) are in the range from 1.1-4.9%, and from 98.5-102.6%, respectively. Most ions do not significantly interfere. The method was successfully applied to the determination of Pd(II) in water and urine samples, alloys, and palladium catalysts.
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