Journal
METALS AND MATERIALS INTERNATIONAL
Volume 14, Issue 2, Pages 229-232Publisher
KOREAN INST METALS MATERIALS
DOI: 10.3365/met.mat.2008.04.229
Keywords
nanostructures; Co3O4; spray conversion method; lithium ion batteries; anode
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A nano-sized Co3O4 powder was prepared using a spray conversion method that could be applied for mass production. The spray-conversion process consisted of spray drying of a metallic liquid solution, a calcination treatment, and a ball milling process. The calcined Co3O4 powder consisted of agglomerated spherical clusters with nano-sized particles. After milling for 24 h, agglomerated powders were fragmented into fine powders sized below 60 nm. The lithium/cobalt oxide cell was charge-discharged at a constant current density of 0.2 mAcm(-2) and showed a first discharge capacity of 1100 mAhg(-1). The discharge capacity of the Li/Co3O4 cell drastically decreased with cycle number. By increasing the carbon content of the anode, the eye I le life was improved. For a Co3O4 electrode containing 40 wt% carbon, the discharge capacity was over 400 mAhg(-1) after 50 cycles. The spray conversion method might be a useful method to prepare nano-sized Co3O4 powder for the anode material of lithium batteries.
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