Journal
METALLOMICS
Volume 3, Issue 9, Pages 909-916Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1mt00065a
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Funding
- University of Akron
- National Institutes of Health [R15 GM 083322]
- Research Corporation [CC6663/6616]
- National Science Foundation [CHE-0819686]
- Division Of Chemistry [0819686] Funding Source: National Science Foundation
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R15GM083322] Funding Source: NIH RePORTER
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The reaction of Re(CO)(3)(H2O)(3)(+) with hen egg white lysozyme in aqueous solution results in a single covalent adduct. Both NMR spectroscopy and single crystal X-ray diffraction show that the rhenium tricarbonyl cation binds to His15 via replacement of one of the coordinated water molecules. The formation of this adduct does not greatly affect the structure of the protein.
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