4.1 Article

Synthesis and Luminescence Properties of Hybrid Systems Based on Liquid Crystal Terbium(III) and Europium(III) Complexes

Journal

RUSSIAN JOURNAL OF GENERAL CHEMISTRY
Volume 85, Issue 12, Pages 2806-2812

Publisher

MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070363215120245

Keywords

lanthanide complexes; liquid crystals; hybrid systems; luminescence

Funding

  1. Russian Foundation for Basic Research [14-03-00 136]
  2. Ministry of Education and Science of the Russian Federation [4.323.2014/K]

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Hybrid liquid crystal systems with different ratios of the components have been prepared on the basis of 5,5'-di(heptadecyl)-2,2'-bipyridine tris(beta-diketonate) lanthanum(III), europium(III), and terbium(III) complexes, and their liquid crystalline and luminescence properties have been studied. A relation has been found between the luminescence intensity and concentration of the components, and a probable mechanism of photoexcitation in the hybrid systems has been proposed.

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