4.2 Article

Preparative synthesis of selectively substituted 1,6-anhydro-α-D-galactofuranose derivatives

Journal

MENDELEEV COMMUNICATIONS
Volume 24, Issue 6, Pages 336-337

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.mencom.2014.11.006

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Funding

  1. Russian Science Foundation [14-23-00199]
  2. Russian Science Foundation [14-23-00199] Funding Source: Russian Science Foundation

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Heating of trisodium salt of allyl 3-O-benzyl-2,5,6-tri-O-sulfonato-beta-D-galactofuranoside with pyridinium chloride in dioxane affords 1,6-anhydro-3-O-benzyl-alpha-D-galactofuranose which was regioselectively acylated to give useful precursors for oligosaccharide synthesis.

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