4.2 Article

Thermal behaviour of the copolymers of acrylonitrile with methyl acrylate and itaconic acid or its derivatives

Journal

MENDELEEV COMMUNICATIONS
Volume 23, Issue 5, Pages 277-278

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.mencom.2013.09.013

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Funding

  1. Ministry of Education and Science of the Russian Federation [14.513.11.0033]

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Itaconic acid monoesters and monoamides, such as 2-carbamoylmethacrylic acid, N-octyl-2-carbamoylmethacrylic acid and 2-methoxycarbonylmethacrylic acid, smoothed the peak of heat release upon the thermal cyclization of acrylonitrile copolymers with commensurable effectiveness, and they can serve as competitive substitutes for itaconic acid in the synthesis of carbon fiber precursors.

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