Journal
MENDELEEV COMMUNICATIONS
Volume 22, Issue 2, Pages 80-82Publisher
ELSEVIER
DOI: 10.1016/j.mencom.2012.03.009
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Funding
- Federal Programme 'Research and Scientific-Pedagogical Cadres of Innovative Russia' [16.740.11.0472]
- Russian Foundation for Basic Research [09-03-00426-a]
- Russian Federation [MD-2747.2010.3]
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Selective transmembrane carriers for alpha-hydroxy acids, acyclic a-amino phosphonates and calix[4]arenes containing alpha-aminophosphonate substituents at the lower rim have been synthesized; analytical HPLC has been used to monitor the selective separation of dicarboxylic, alpha-hydroxy and alpha-amino acid mixtures by membrane extraction; the attachment of alpha-aminophosphonate fragments to the macrocyclic calix[4]arene platform results in receptors with markedly modified efficiency and selectivity relative to those of only aminophosphonates.
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