4.2 Article

Chemical bonding in complexes with high coordination numbers: a charge density study

Journal

MENDELEEV COMMUNICATIONS
Volume 21, Issue 3, Pages 160-162

Publisher

ELSEVIER
DOI: 10.1016/j.mencom.2011.04.017

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Funding

  1. Russian Foundation for Basic Research [09-03-00603-a]
  2. Russian Federation [MD-237.2010.3]

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The topological analysis of an experimental charge-density distribution in crystalline tris(pyridine)bis(o-hydroxybenzoato)cadmium(II) revealed that the metal-ligand bonds occupy nearly the same place in the energetic scale as the hydrogen bonds do, thus being extremely sensitive to steric and crystal-packing effects.

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