Journal
RUSSIAN CHEMICAL BULLETIN
Volume 64, Issue 4, Pages 846-851Publisher
SPRINGER
DOI: 10.1007/s11172-015-0943-1
Keywords
mercaptoethanol; hydroperoxides; free radicals; lipid oxidation; method of inhibitors; cis-trans-isomerization
Categories
Funding
- Russian Foundation for Basic Research [14-03-00757]
- Council on Grants at the President of the Russian Federation (Program of the State Support of Leading Scientific Schools) [NSh-5226-2014-03]
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The kinetics of the oxidation of ethylbenzene, limonene, and methyl linoleate containing mercaptoethanol additives were studied, as well as cis-trans-isomerization of the double bonds in methyl linoleate. Mercaptoethanol (RSH) additives were found to accelerate the oxidation of hydrocarbons and methyl linoleate due to the reaction of RSH with hydroperoxides (primary oxidation products) resulting in a low yield of free radicals. The cis-trans-isomerization catalyzed by thiyl radicals produced in the exchange radical reactions with RSH decelerates in the presence of oxygen.
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