Journal
RUSSIAN CHEMICAL BULLETIN
Volume 64, Issue 3, Pages 475-497Publisher
SPRINGER
DOI: 10.1007/s11172-015-0891-9
Keywords
molecular switches; configurational isomerism; valence tautomerism; redox-active ligands; spin crossover; electromerism; photochromism
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Funding
- Russian Science Foundation [14-13-00573]
- Russian Science Foundation [14-13-00573] Funding Source: Russian Science Foundation
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The principal molecular mechanisms that control spin state switching rearrangements of transition metal complexes are considered. A new approach to the structural design of valence tautomeric compounds involving the formation of adducts of four-coordinate metal complexes with bidentate redox-active ligands is proposed. By means of theoretical modeling methods, new molecular systems with photo-switchable magnetic properties based on transition metal complexes with photochromic ligands are suggested.
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