4.7 Article

Methyl red removal from water by iron based metal-organic frameworks loaded onto iron oxide nanoparticle adsorbent

Journal

APPLIED SURFACE SCIENCE
Volume 330, Issue -, Pages 85-93

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2014.12.196

Keywords

Metal organic framework; Langmuir isotherm; Methyl red removal; Iron oxide nanoparticles; Surface modification

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The objective followed by this research is the synthesis of iron based metal organic framework loaded on iron oxide nanoparticles (Fe3O4@MIL-100(Fe)) and the study of its capability for the removal of methyl red. Effective parameters in the selection of a new adsorbent, i.e. adsorption capacity, thermodynamics, and kinetics were investigated. All the studies were carried out in batch experiments. Removal of methyl red from aqueous solutions varied with the amount of adsorbent, methyl red contact time, initial concentration of dye, adsorbent dosage, and solution pH. The capability of the synthesized adsorbent in the removal of methyl red was compared with the metal organic framework (MIL-100(Fe)) and iron oxide nanoparticles. The results show that Fe3O4@MIL-100(Fe) nanocomposite exhibits an enhanced adsorption capacity. (C) 2015 Elsevier B.V. All rights reserved.

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