4.3 Article

Characteristic Sorption of H3BO3/B(OH)4- on Magnesium Oxide

Journal

MATERIALS TRANSACTIONS
Volume 54, Issue 9, Pages 1809-1817

Publisher

JAPAN INST METALS
DOI: 10.2320/matertrans.M-M2013814

Keywords

trigonal boron; magnesium oxide; sorption mechanism; ligand-promoted dissolution; B-11-NMR

Funding

  1. Funding Program for Next Generation of World-Leading Researchers (NEXT program) in Japan Society for the Promotion of Science (JSPS)
  2. New Energy and Industrial Technology Development Organization (NEDO) under the Innovative Zero-emission Coal-fired Power Generation Project
  3. JSPS [S-11179]

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The reaction mechanism of H3BO3/B(OH)(4)(-) with MgO in aqueous phase was investigated using sorption isotherm, XRD, B-11-NMR and FTIR. Release of Mg2+ was observed soon after contact of MgO with H3BO3 and maximum released Mg2+ was proportional to the initial boron concentration, suggesting ligand-promoted dissolution of MgO by H3BO3. The molecular form of H3BO3 was more reactive with MgO in releasing Mg2+ ions than B(OH)(4)(-). B-11-NMR results indicated that trigonal B (B-[3]) was predominant over tetrahedral B (B-[4]) in solid residues after sorption of H3BO3. The molar ratio of B-[4]/B-[3] increased with H3BO3 sorption density. XRD patterns for the solid residues were assigned to Mg(OH)(2) and peaks broadened with increasing H3BO3 sorption density, except for (hk0) planes due to c-axis lattice strain induced by incorporation of H3BO3 between layers. These results indicated that H3BO3 interfered in the c-axis stacking of in Mg(OH)(2). Molecular H3BO3 acted as a trigger when reacting with the MgO surface, releasing Mg2+ to produce an unstable complex leading to the precipitation formation of Mg(OH)(2), which is a sink for the immobilization of H3BO3/B(OH)(4)(-).

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