Journal
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS
Volume 177, Issue 6, Pages 483-487Publisher
ELSEVIER
DOI: 10.1016/j.mseb.2012.02.007
Keywords
Organic positive-electrode material; Lithium ion battery; Multi-electron redox
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The performance of 9,10-anthraquinone (AQ), and 5,7,12,14-pentacenetetrone (PT) as active materials for rechargeable lithium batteries was investigated. Positive-electrodes in which AQ and PT were incorporated showed initial discharge capacities of greater than 200 mAh/g((AQ or PT)). The obtained discharge capacities suggest that a multi-electron redox reaction takes place in each derivative. The discharge capacity of the positive-electrode with AQ rapidly decreased during the charge/discharge cycles; however, the positive-electrode with PT showed a relatively good cycle-life performance; it maintained about 80% of the initial capacity even after 100 cycles. (C) 2012 Elsevier B.V. All rights reserved.
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