Journal
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS
Volume 153, Issue 1-3, Pages 47-52Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.mseb.2008.09.030
Keywords
Spintronics; Dilute magnetic semiconductor; Ferromagnetism; X-ray diffraction; Transmission electron microscopy
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Colloidal Fe-doped ZnO nanocrystals, Zn1-xFexO (x = 0.00, 0.05, 0.07 and 0.1) have been prepared by thermal decomposition of metal precursors at 200 degrees C with hexadecylamine (HDA) as solvent and surfactant. The nanocrystals so prepared can be easily dispersed in non-polar solvents like chloroform and toluene. The nanocrystals have been structurally Characterized using X-ray diffraction (XRD), high resolution transmission electron microscopy (HRTEM). energy dispersive X-ray analysis (EDX) and X-ray photoelectron spectroscopy (XPS). Magnetization measurements on a representative sample. Zn0.95Fe0.05O using a vibrating sample magnetometer (VSM) reveal that the nanocrystals exhibit a weak ferromagnetic behavior at 300 K. This observation is further confirmed by the electron paramagnetic resonance spectrum of Zn0.95Fe0.05O nanocrystals, which shows a distinct ferromagnetic resonance signal at room temperature. (C) 2008 Elsevier B.V. All rights reserved.
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