4.5 Article Proceedings Paper

Photoluminescent properties of Sr2SiO4:Eu2+ phosphors prepared by solid-state reaction method

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.mseb.2007.07.052

Keywords

europium oxide; optical properties; strontium silicate; energy transfer

Funding

  1. National Research Foundation of Korea [R01-2005-000-10530-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Sr2SiO4:Eu2+ phosphors were prepared by a flux method. Two emission bands at 495 nm and 560 nm were observed, which originated from Eu(I) and Eu(II) that were substituted for Sr(I) and Sr(II), respectively. The preference of Eu2+, ions for Sr(I) and Sr(II) strongly depended on the amounts of flux and firing temperatures. The increase of Eu2+ concentration led to the energy transfer from Eu(I) to Eu(II) emitting center, resulting in the red-shift, and the phase transformation from beta- to alpha'-Sr2SiO4 were observed. (C) 2007 Elsevier B.V. All rights reserved.

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