Correlation of austenite stability and ductile-to-brittle transition behavior of high-nitrogen 18Cr-10Mn austenitic steels

Ductile-to-brittle transition behavior of high-nitrogen 18Cr-10Mn austenitic steels containing different contents of Ni, Mo, Cu as well as nitrogen is discussed in terms of austenite stability and associated deformation-induced martensitic transformation (DIMT). Electron back-scattered diffraction and transmission electron microscopy analyses of cross-sectional area of the Charpy impact specimens fractured at -196 degrees C indicated that the brittle fracture planes were almost parallel to one of {1 1 1} slip planes and some metastable austenites near the fracture surface were transformed to alpha'-martensite by localized plastic deformation occurring during crack propagation. Quantitative evaluation of deformation-induced martensite together with characteristics of true stress-strain and load-displacement curves obtained from tensile and Charpy impact tests, respectively, supported that DIMT might take place in high-nitrogen austenitic steels with relatively low austenite stability. The occurrence of DIMT decreased low-temperature toughness and thus increased largely ductile-to-brittle transition temperature (DBTT), as compared to that predicted by empirical equations strongly depending on nitrogen content. As a result, the increased DBTT could be reasonably correlated with austenite stability against DIMT. (C) 2011 Elsevier B.V. All rights reserved.