Sensitive detection of mercury (II) ion using water-soluble captopril-stabilized fluorescent gold nanoparticles

In our work, a simple, facile, and green method was developed for the synthesis of water-soluble and well-dispersed fluorescent gold nanoparticles (Au NPs) within 5 min, using captopril as a capping agent. The as-prepared Au NPs showed strong emission at 414 nm, with a quantum yield of 5.5%. The fluorescence of the Au NPs can be strongly quenched by mercury (II) ion (Hg2+) due to the stronger interactions between thiolates (RS-) and Hg2+. It was applied to the detection of Hg2+ in water samples in the linear ranges of 0.033-0.133 mu M and 0.167-2.500 mu M, with a detection limit of 0.017 mu M. Therefore, the as-prepared Au NPs can meet the requirement for monitoring Hg2+ in environmental samples. (C) 2013 Elsevier B.V. All rights reserved.