Journal
MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS
Volume 31, Issue 8, Pages 1637-1642Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.msec.2011.07.007
Keywords
Uranyl cation selective electrode; Benzo-15-crown-5; Potentiometry
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Funding
- Ferdowsi University of Mashhad, Mashhad, Iran
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uranyl cation selective electrode based on benzo-15-crown-5(B15C5) incorporated into a polyvinylchloride (PVC) membrane has been developed. The electrode was prepared by coating the surface of a graphite rod by a membrane containing dioctylphtalate (DOP) as plasticizer, B15C5 as an ionophore, carbon powder and polyvinylchloride (PVC) in tetrahydrofuran (THF). The best composition of the coated membrane (w/w%) was found to be: 4% ionophore, 20% plasticizer, 56% PVC and 20% carbon powder. The electrode exhibits a Nernstian slope (29.5 +/- 2 my) over the concentration range from 1.0 x 10(-4) to 1.0 X 10(-1) M. The detection limit of the electrode is 1.0 x 10(-4) M. The effects of the pH and the possible interfering cations and anions were investigated and the optimized conditions for electrode were evaluated. The response time of the electrode is about 15 s and it can be used for more than 6 weeks without observing any divergence in potentiometric response. The electrode was applied as indicator electrode in potentiometric titrations. (C) 2011 Elsevier B.V. All rights reserved.
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