Journal
MATERIALS RESEARCH BULLETIN
Volume 50, Issue -, Pages 165-171Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2013.10.043
Keywords
chalcogenides; semiconductors; thin film; sol-gel chemistry; X-ray diffraction; crystal structure
Categories
Funding
- Scientific Research Commission (BAP) of Mustafa Kemal University [1204D0102]
- Slovenian Research Agency
- [P2-0084-0106/04]
Ask authors/readers for more resources
As a promising solar absorber, the Cu2ZnSnS4 compound has been popular recently for the production of green and economical thin-film solar cells owing to the abundancy and non-toxicity of all the constituents. In this study, we have produced Cu2ZnSnS4 films via the sal-gel technique. As a stabilizer, the effects of the diethanolamine on the properties of the films were investigated. The amount of diethanolamine significantly affected the crystal structure, crystallite sizes and phase purity of the films. X-ray diffraction and Raman spectroscopy analyses confirmed the formation of phase-pure CZTS films. It was found that the film produced by using 2 ml of diethanolamine in sol exhibited pure CZTS phase, compact and dense morphology and enhanced photo-sensitivity. Light on/off current ratio of the n-Si/Cu2ZnSnS4 junction was found to be 47 under 100 mW/cm(2) of illumination. Electrical activation energies of the films were investigated and the variations were attributed to delocalized phonon states generating from the presence of other phases and lattice defects. (C) 2013 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available