Journal
MATERIALS RESEARCH BULLETIN
Volume 47, Issue 7, Pages 1747-1754Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2012.03.045
Keywords
Composites; Interface; Chemical synthesis; Electron microscopy; Dielectric properties
Categories
Funding
- National Natural Science Foundation [51132002, 51072024, 50972014, 50872159]
- National Defense Funds [A2220061080]
- Yumiao Foundation of Beijing Institute of Technology
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Zinc oxide (ZnO) nanoparticles were coated on the surfaces of multiwalled carbon nanotubes (MWCNTs). High resolution transmission electron microscopy images show that the wurtzite ZnO immobilized on the MWCNTs is single-crystalline with a preferential [0 0 0 2] growth direction. A capacitor was generated by the interface of ZnO and MWCNTs, and a resistor-capacitor model could well describe the relationships between the structure and the dielectric properties, electromagnetic interference shielding and microwave-absorption of the composites in the frequency range of 2-18 GHz. The network built by ZnO-immobilized MWCNTs could contribute to the improvement of electrical properties. Resonant peaks associated with the capacitor formed by the interface were observed in the microwave absorption spectra, which suggest that reflection-loss peaks greatly broadens the absorption bandwidth. Crown Copyright (C) 2012 Published by Elsevier Ltd. All rights reserved.
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