Journal
MATERIALS RESEARCH BULLETIN
Volume 44, Issue 1, Pages 74-77Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2008.04.002
Keywords
Layered compounds; Oxides; Intercalation reactions; X-ray diffraction
Categories
Funding
- National Science Foundation [0612544]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [0612544] Funding Source: National Science Foundation
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A series of fluorine intercalated Ruddlesden-Popper layered perovskites, Ln(1.2)Sr(1.8)Mn(2)O(7)F(2) (Ln = La, Pr. Nd, Sm, Eu, and Gd) were synthesized from the parent oxides, Ln(1.2)Sr(1.8)Mn(2)O(7), with the organic reagent, poly(vinylidene fluoride), as the fluorine source. Oxidative intercalation readily occurred by decomposition of the organic fluoride immediately adjacent to the parents. (C) 2008 Elsevier Ltd. All rights reserved.
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