4.6 Article

Photocatalytic hydrogen production over Na2Ti2O4(OH)2 nanotube sensitized by CdS nanoparticles

Journal

MATERIALS RESEARCH BULLETIN
Volume 44, Issue 2, Pages 442-445

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2008.04.016

Keywords

Nanostructures; Semiconductors; X-ray diffraction

Funding

  1. National Natural Science Foundation of China [90610022, 50521604]
  2. National Basic Research Program of China [2003CB21 4500]

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Na2Ti2O4(OH)(2) nanotubes were obtained by hydrothermal reaction of TiO2 with concentrated NaOH solution. CdS nanoparticles were then decorated on Na2Ti2O4(OH)(2) nanotubes through partial ion-exchange method. The composite photocatalysts were characterized by X-ray diffraction (XRD), ultraviolet-visible spectra (UV-vis), transmission electron microscope (TEM), etc. The results showed that CdS nanoparticles of 5-6 nm were anchored on the surface of the Na2Ti2O4(OH)(2) nanotubes. Under irradiation of visible light (lambda >= 430 nm). the prepared CdS/Na2Ti2O4(OH)(2) showed high photoactivity for hydrogen production. (C) 2008 Elsevier Ltd. All rights reserved

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