4.6 Article

Nanocast carbon microsphere flowers from a lanthanum-based template

Journal

MATERIALS LETTERS
Volume 234, Issue -, Pages 224-227

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.matlet.2018.09.055

Keywords

Nanocast; Graft polymer; Lanthanum; Catalyst; CVD; Carbon

Funding

  1. Robert A. Welch Foundation [AT-1153]

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Hollow carbon microsphere flowers were nanocast from glucose, acrylamide, and acetylene sources. Carbon growth was catalyzed by a lanthanum graft copolymer template using wet acetylene. The resulting spherical shape is beneficial for 3-D porosity, and has a highly graphitic content as indicated by raman spectroscopy (I-D :I-G = 0.99). The carbon has a high surface area of 1000 m(2)/g, as well as strong pi-pi stacking of aromatic carbons. (C) 2018 Elsevier B.V. All rights reserved.

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