Journal
MATERIALS LETTERS
Volume 130, Issue -, Pages 188-191Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.matlet.2014.05.106
Keywords
Carbon materials; Synthesis; Microstructure; Adsorption property
Funding
- National Natural Science Foundation of China [91326102, U1232136]
- Science and Technology Development Foundation of China Academy of Engineering Physics [2012B0302035, 2013A0301012]
- Science and Technology Innovation Research Foundation of Institute of Nuclear Physics and Chemistry
- Japan Society for the Promotion Science [23350104]
- Fundamental Research Program of Korean Institute of Materials Science (KIMS)
- Ningbo Natural Science Foundation [2013A610128]
- EPSRC, UK [EP/K008749/1]
- Engineering and Physical Sciences Research Council [EP/K008749/2, EP/K008749/1] Funding Source: researchfish
- EPSRC [EP/K008749/2, EP/K008749/1] Funding Source: UKRI
- Grants-in-Aid for Scientific Research [23350104] Funding Source: KAKEN
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Nanocarbide-derived carbon (CDC) was synthesized at room temperature by etching Nb4AlC3 and Ti3SiC2 powders in alkali and acid solutions, respectively. The obtained CDC showed similar morphologies as the one obtained by high temperature chlorination. The CDC synthesis mechanisms included removal of Nb, Al, Ti, Si and formation of amorphous carbon phase which reordered in various structures including carbon barrel, onion, ribbon, tube, and rod. The CDC obtained from Ti3SiC2 showed high nitrogen adsorption capability of 86.8 cm(3)/g (STP) (P/P-0 approximate to 1). (C) 2014 Elsevier B.V. All rights reserved.
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